Methacrylic Acid (MAA), with the molecular formula C₄H₆O₂, is an organic compound characterized by a carboxyl group (-COOH) attached to a carbon-carbon double bond. This structure classifies it as an α,β-unsaturated carboxylic acid, enabling it to undergo various chemical reactions such as polymerization and esterification.

  • CAS Number: 79-41-4
  • Molecular Weight: 86.09 g/mol
  • IUPAC Name: 2-Methylprop-2-enoic acid
  • Synonyms: 2-Methylacrylic acid, α-Methacrylic acid, 2-Methyl-2-propenoic acid

Physical & Chemical Properties

  • Appearance: Colorless to pale yellow liquid
  • Boiling Point: 161°C
  • Melting Point: 14–15°C
  • Density: 1.015 g/cm³ at 20°C
  • Flash Point: 67°C
  • Solubility: Soluble in water and most organic solvents
  • Vapor Pressure: 0.7 mmHg at 20°C
  • Odor: Acrid, pungent

Applications

Methacrylic Acid serves as a versatile monomer and intermediate in various industrial applications:

  1. Polymer Industry:

    • Methyl Methacrylate (MMA): MAA is a precursor to MMA, which polymerizes to form polymethyl methacrylate (PMMA), a transparent and durable plastic commonly known as acrylic glass.

    • Copolymers: MAA is copolymerized with other monomers to produce materials with tailored properties for specific applications.

  2. Coatings and Paints:

    • Acrylic Coatings: MAA is used in the production of acrylic coatings that offer excellent adhesion, weather resistance, and durability.

    • Varnishes: Incorporated into varnishes to enhance gloss and protect surfaces.

  3. Adhesives and Sealants:

    • Pressure-Sensitive Adhesives: MAA-modified copolymers provide tackiness and shear strength.

    • Construction Sealants: Improves adhesion to various substrates and enhances flexibility.

  4. Textile and Leather Finishes:

    • Fabric Treatments: MAA-based polymers impart water repellency and stain resistance to textiles.

    • Leather Coatings: Enhances the durability and appearance of leather products.

  5. Pharmaceuticals:

    • Enteric Coatings: MAA copolymers are used in enteric coatings for tablets to control the release of active ingredients in the digestive tract.

  6. Water Treatment:

    • Flocculants and Dispersants: MAA-based polymers aid in the aggregation and removal of suspended particles in water treatment processes.

Safety and Handling

  • Storage: Store in a cool, well-ventilated area away from heat and ignition sources.
  • Handling: Use appropriate personal protective equipment (PPE), including gloves, goggles, and protective clothing.
  • Incompatibilities: Avoid contact with strong oxidizing agents, acids, and bases.
  • First Aid Measures: In case of contact, immediately flush with plenty of water and seek medical attention if necessary.

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